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Beilstein J. Org. Chem. 2015, 11, 596–603, doi:10.3762/bjoc.11.66
Graphical Abstract
Figure 1: Some indolizidine alkaloids.
Figure 2: Approaches to racemic tashiromine and epitashiromine.
Figure 3: Synthetic routes to (+)-tashiromine and (+)-epitashiromine.
Figure 4: Synthetic routes to (−)-tashiromine and (−)-epitashiromine.
Figure 5: Oxidative functionalizations of cyclic β-amino acids.
Scheme 1: Retrosynthesis of tashiromine and epitashiromine.
Scheme 2: Synthesis of (±)-tashiromine ((±)-6).
Scheme 3: Synthesis of (±)-epitashiromine ((±)-10).